Dynamic Stark shift of the 3R1 Rydberg state of CH3I
1 Departamento de Química Física. Facultad de Ciencias Químicas. Universidad Complutense de Madrid, 28040 Madrid, Spain
2 Instituto Química Física Rocasolano, CSIC, C/ Serrano, 119, 28006 Madrid, Spain
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Stark shift of the 3R1 Rydberg state of CH3I is measured for different Stark field intensities. Photodissociation products, generated after predissociation of the state, were detected when the molecules were excited with photons resonant with the energy difference between the ground and the shifted 3R1 state, allowing the shift to be quantified. Qualitative agreement has been found with a 1D model.
© Owned by the authors, published by EDP Sciences, 2013
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