https://doi.org/10.1051/epjconf/20134105023
Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence
1 Ultrafast dynamics Laboratory, Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, South Korea.
2 Synthetic Organic Chemistry Laboratory, Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, South Korea.
Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.
© Owned by the authors, published by EDP Sciences, 2013
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