Effect of spin-orbital interaction on continuous and jumpwise reversal magnetization in [Mn(II)(HL)(H2O)][Mn(III)(CN)6]·2H2O molecular ferrimagnet
Institute of Problems of Chemical Physics of Russian Academy of Sciences, 142432, Chernogolovka, Russia
* Corresponding author: firstname.lastname@example.org
Published online: 4 July 2018
Magnetic jumps were revealed during the magnetization reversal of [Mn(II)(HL)(H2O)][Mn(III)(CN)6]·2H2O molecular ferrimagnet. Amplitudes of the jumps were 0.01 – 0.1 % of the saturation magnetization. Fourier transform of the time series of jumps magnetization indicates that frequency spectrum is close to the white noise. Statistic distribution of the jumps versus time reveals the appearance of the most jumps at the beginning of the demagnetization. Effect of spin-orbit coupling on statistical distribution of magnetization jumps was considered by comparison of two compounds with different single ion anisotropies. The increase of spin-orbit interaction leads to the decrease of power of spectral density of magnetization jumps.
© The Authors, published by EDP Sciences, 2018
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