https://doi.org/10.1051/epjconf/201819003013
Influence of solid matrices on spectral features of metalloporphyrins
1
B.I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk 220072, Belarus
2
Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw 01-224, Poland
* Corresponding author: starukhin@mail.ru
Published online: 26 September 2018
A way of simultaneously forming in the ground electronic state a planar, as well as two distorted forms was established for a set of metalloporphyrins in solid matrices at cryogenic temperatures. Experimental data together with results of theoretical DFT calculations are combined for analysis and assignment of possible types of distorted porphyrin macrocycles conformations.
© The Authors, published by EDP Sciences, 2018
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