https://doi.org/10.1051/epjconf/201920506016
Simulating exciton migration and annihilation dynamics in higher order spectroscopies of a molecular trimer
1 Photonics Institute, TU Wien, GuBhausstraße 27-29, 1040 Vienna, Austria
2 Institute of Physics, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, Prague 121 16, Czech Republic
3 Professur für Dynamische Spektroskopien, Fakultät für Chemie, Technische Universität München, Lichtenbergstr. 4, D-85748, Garching b. München, Germany
* Corresponding author: juergen.hauer@tum.de
Published online: 16 April 2019
We present simulations of 3rd and 5th order multidimensional time-dependent signals of a molecular trimer. The developed model allows for the simulation of both signal types within one theoretical framework. We therefore extended standard Redfield theory of exciton migration by a new term to include the process of exciton-exciton annihilation.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
