https://doi.org/10.1051/epjconf/201920509004
Ultrafast proton transport in water-methanol mixtures
1 Max Born Institut für Nichtlineare Optik und Kurzzeitspektroskopie, 12489 Berlin, Germany
2 Martin-Luther-Universität Halle-Wittenberg, Institut für Chemie, 06120 Halle (Saale), Germany
* Corresponding author: nibberin@mbi-berlin.de
𠀠 Corresponding author: daniel.sebastiani@chemie.uni-halle.de
Published online: 16 April 2019
Femtosecond UV/IR pump-probe experiments and ab initio molecular dynamics simulations of 7-hydroxyquinoline in water-methanol mixtures demonstrate an unexpectedly dominant OH-/CH3O- transport pathway but consistent with a solvent-dependent photoacidity free energy-reactivity correlation behaviour.
© The Authors, published by EDP Sciences, 2019
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