https://doi.org/10.1051/epjconf/201920509004
Ultrafast proton transport in water-methanol mixtures
1 Max Born Institut für Nichtlineare Optik und Kurzzeitspektroskopie, 12489 Berlin, Germany
2 Martin-Luther-Universität Halle-Wittenberg, Institut für Chemie, 06120 Halle (Saale), Germany
* Corresponding author: nibberin@mbi-berlin.de
𠀠 Corresponding author: daniel.sebastiani@chemie.uni-halle.de
Published online: 16 April 2019
Femtosecond UV/IR pump-probe experiments and ab initio molecular dynamics simulations of 7-hydroxyquinoline in water-methanol mixtures demonstrate an unexpectedly dominant OH-/CH3O- transport pathway but consistent with a solvent-dependent photoacidity free energy-reactivity correlation behaviour.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
