https://doi.org/10.1051/epjconf/201920509009
High sensitivity fluorescence up-conversion spectroscopy of 3MLCT emission of metal-organic complexes
1 Université de Strasbourg CNRS, UMR 7504, IPCMS, 67034 Strasbourg France
2 Université de Lorraine - CNRS, UMR 7053, L2CM, 54506 Vandoeuvre-lès-Nancy, France
* Corresponding author: stefan.haacke@ipcms.unistra.fr
Published online: 16 April 2019
We demonstrate the implementation of a broadband fluorescence up-conversion set-up with high signal-to-noise ratio and dynamic range allowing for the detection of weak luminescence from triplet states in Fe(II) NHC complexes. Based on the experimentally determined radiative rates and the emission spectra, these states have dominant MLCT character.
© The Authors, published by EDP Sciences, 2019
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