https://doi.org/10.1051/epjconf/201920509019
Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
1 TU Kaiserslautern, Chemistry Dept., Erwin-Schrödinger Str. 52-54, 67663 Kaiserslautern, Germany
2 TU Kaiserslautern, Physics Dept., Erwin-Schrödinger Str. 46, 67663 Kaiserslautern, Germany
3 Karlsruhe Institute of Technology, Institute of Physical Chemistry, Fritz-Haber Weg 2, 76131 Karlsruhe, Germany
4 Landesforschungszentrum OPTIMAS, Erwin-Schrödinger Str. 46, 67663 Kaiserslautern, Germany
* Corresponding authors: kruppa@chemie.uni-kl.de, riehn@chemie.uni-kl.de
Published online: 16 April 2019
Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
