Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
1 TU Kaiserslautern, Chemistry Dept., Erwin-Schrödinger Str. 52-54, 67663 Kaiserslautern, Germany
2 TU Kaiserslautern, Physics Dept., Erwin-Schrödinger Str. 46, 67663 Kaiserslautern, Germany
3 Karlsruhe Institute of Technology, Institute of Physical Chemistry, Fritz-Haber Weg 2, 76131 Karlsruhe, Germany
4 Landesforschungszentrum OPTIMAS, Erwin-Schrödinger Str. 46, 67663 Kaiserslautern, Germany
Published online: 16 April 2019
Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.
© The Authors, published by EDP Sciences, 2019
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