Photodissociation dynamics of nitric oxide from roussin’s red ester probed by time-resolved infrared spectroscopy

Hojeong Yoon; Seongchul Park; CheongHa Lim; Manho Lim

doi:10.1051/epjconf/201920509020

EPJ

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Proceedings

Open Access

EPJ Web of Conferences 205, 09020 (2019)
https://doi.org/10.1051/epjconf/201920509020

Photodissociation dynamics of nitric oxide from roussin’s red ester probed by time-resolved infrared spectroscopy

Hojeong Yoon, Seongchul Park, CheongHa Lim and Manho Lim

Department of Chemistry, Pusan National University, Busan 46241, Republic of Korea

Published online: 16 April 2019

Abstract

To explore nitric oxide (NO)-donating capability of Roussin’s red ester [Fe₂(μ-RS)₂(NO)₄] (RRE), photodissociation of NO from RRE and its subsequent reaction dynamics were probed by monitoring the N–O stretching mode after excitation with a 400-nm photon. As a result of the experiment, the NO generation quantum yield was obtained.

© The Authors, published by EDP Sciences, 2019

This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.