Photodissociation dynamics of nitric oxide from roussin’s red ester probed by time-resolved infrared spectroscopy
Department of Chemistry, Pusan National University, Busan 46241, Republic of Korea
Published online: 16 April 2019
To explore nitric oxide (NO)-donating capability of Roussin’s red ester [Fe2(μ-RS)2(NO)4] (RRE), photodissociation of NO from RRE and its subsequent reaction dynamics were probed by monitoring the N–O stretching mode after excitation with a 400-nm photon. As a result of the experiment, the NO generation quantum yield was obtained.
© The Authors, published by EDP Sciences, 2019
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