Bond formation dynamics of dicyanoaurate in the first excited singlet state
Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang 37673, South Korea
* Corresponding author: firstname.lastname@example.org
Published online: 16 April 2019
Time-resolved fluorescence of [Au(CN)2−]3 in water reveals a coherent vibration of 74 cm-1. A massive non-Condon effect, proved unambiguously by time-resolved fluorescence spectra, demonstrates that the wave packet motion arises from the coherent bond formation.
© The Authors, published by EDP Sciences, 2019