EPJ Web of Conferences 205, 09021 (2019)
https://doi.org/10.1051/epjconf/201920509021
https://doi.org/10.1051/epjconf/201920509021
Bond formation dynamics of dicyanoaurate in the first excited singlet state
Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang 37673, South Korea
* Corresponding author: thjoo@postech.ac.kr
Published online: 16 April 2019
Time-resolved fluorescence of [Au(CN)2−]3 in water reveals a coherent vibration of 74 cm-1. A massive non-Condon effect, proved unambiguously by time-resolved fluorescence spectra, demonstrates that the wave packet motion arises from the coherent bond formation.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
