Graphene edges; localized edge state and electron wave interference
Tokyo Institute of Technology, Department of Chemistry, Ookayama, Meguro-ku, Tokyo 152-8551, Japan
The electronic structure of massless Dirac fermion in the graphene hexagonal bipartite is seriously modified by the presence of edges depending on the edge chirality. In the zigzag edge, strongly spin polarized nonbonding edge state is created as a consequence of broken symmetry of pseudo-spin. In the scattering at armchair edges, the K-K’ intervalley transition gives rise to electron wave interference. The presence of edge state in zigzag edges is observed in ultra-high vacuum STM/STS observations. The electron wave interference phenomenon in the armchair edge is observed in the Raman G-band and the honeycomb superlattice pattern with its fine structure in STM images.
© Owned by the authors, published by EDP Sciences, 2012